СИНТЕЗ НАНОКРИСТАЛЛИЧЕСКИХ ПЛЕНОК ФЕРРИТА НИКЕЛЯ ИЗ ВОДНОГО РАСТВОРА СУЛЬФАТОВ МЕТОДОМ ЭЛЕКТРООСАЖДЕНИЯ - АНОДИРОВАНИЯ: МАТЕРИАЛ ДЛЯ ВЫЯВЛЕНИЯ УТЕЧКИ ТОКСИЧНЫХ БЫТОВЫХ ГАЗОВ И МОНИТОРИНГА ЗДОРОВЬЯ
DOI:
https://doi.org/10.22213/2410-9304-2018-3-169-178Ключевые слова:
феррит никеля, электроосаждение, анодирование, тонкая пленка, циклическая вольтамперометрия, наночастицыАннотация
В данной работе была исследована тонкая пленка нанокристаллического феррита никеля NiFe2O4, синтезированная методом электроосаждения-анодирования. Электроосажденные сплавы NiFe2 получали из водной сульфатной ванны. В водном (1 М КОН) растворе при комнатной температуре данные сплавы подвергали электрохимическому оксидированию (анодированию) до соответствующих гидроксидов и затем выдерживали на воздухе при 400 °С в течение 2 часов. Были оптимизированы следующие параметры, влияющие на электроосаждение сплавов NiFe2: температура ванны, методика перемешивания и плотность тока. Кристаллическая структура, размеры кристаллов и микроструктура полученных ферритов были исследованы методами рентгенодифракции и сканирующей электронной микроскопии. Рентгенодифракция показала, что NiFe2O4 имеет структуру шпинели, и размер кристаллов составляет 16 нм. Сканирующая электронная микроскопия полученных ферритовых частиц показала наличие искаженной прямоугольной структуры и полуквадратичной морфологии.Библиографические ссылки
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